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| M A T E R I A L S A F E T Y D A T A S H E E T |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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PRODUCT NAME : FLUORESCENT ORANGE SPRAY PAINT
IDENTIFICATION NUMBER: 203036
DATE PRINTED : 09/19/01
PRODUCT USE/CLASS : I.C. WATER BASED MARKING PAINT
SUPPLIER: MANUFACTURER:
Rust-Oleum Corporation Rust-Oleum Corporation
11 Hawthorn Parkway 11 Hawthorn Parkway
Vernon Hills, Illinois Vernon Hills, Illinois
60061 USA 60061 USA
(847) 367-7700 Rust-Oleum Corp. (847) 367-7700 Rust-Oleum Corp.
8:00 AM-4:30 PM/24-hr Emer.Assist 8:00 AM-4:30 PM/24-hr Emer.Assist
PREPARER: MTM, PHONE: 847-816-2445, PREPARE DATE: 09/19/01
+-------------------------------------------------------------------------+
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 LIQUIFIED PETROLEUM GAS 68476-85-7 25.0 %
02 TOLUENE 108-88-3 15.0 %
03 ALIPHATIC PETROLEUM DISTILLATES 64742-89-8 10.0 %
04 Hydrotreated Light Distillate 64742-47-8 10.0 %
05 Calcium Carbonate (Limestone) 1317-65-3 5.0 %
06 Stoddard Solvent 8052-41-3 5.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA MEXICAN
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 1000 PPM N.E. 1000 PPM N.E. N.E. NO
02 50 PPM 150 PPM 200 PPM 300 PPM N.E. YES
03 300 PPM N.E. 300 PPM N.E. N.E. NO
04 N.E. N.E. N.E. N.E. N.E. NO
05 10mg/m3 N.E. 15mg/m3 N.E. N.E. NO
06 100ppm N.E. 100ppm N.E. 100 PPM NO
(See Section 16 for abbreviation legend)
(Continued on Page 2)
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Product: 203036 Preparation Date: 09/19/01 Page 2
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| SECTION 3 - HAZARDS IDENTIFICATION |
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*** EMERGENCY OVERVIEW ***: Harmful if inhaled. Harmful if swallowed.
Extremely flammable liquid and vapor. Vapors may cause flash fire or
explosion. Harmful if inhaled. May effect the brain or nervous system
causing
dizziness, headache or nausea. Contents Under Pressure.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin
irritation. Prolonged or repeated contact may cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas,
vapor, mist or dust concentrations may be harmful if inhaled. Avoid
breathing vapors or mists. High vapor concentrations are irritating to the
eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if
swallowed. Aspiration hazard if swallowed; can enter lungs and cause
damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous
system disorder (e,g.,narcosis involving a loss of coordination, weakness,
fatigue, mental confusion, and blurred vision) and/or damage. Reports have
associated repeated and prolonged occupational overexposure to solvents
with permanent brain and nervous system damage. Overexposure to toluene in
laboratory animals has been associated with liver abnormalities, kidney,
lung and spleen damage. Effects
in humans have included liver and cardiac abnormalities.
PRIMARY ROUTE(S) OF ENTRY: SKIN ABSORPTION INHALATION EYE CONTACT
+-------------------------------------------------------------------------+
| SECTION 4 - FIRST AID MEASURES |
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FIRST AID - EYE CONTACT: Hold eyelids apart and flush with plenty of water
for at lease 15 minutes. Get medical attention.
FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention
if irritation develops or persists.
FIRST AID - INHALATION: If you experience difficulty in breathing, leave
the area to obtain fresh air. If continued difficulty is experienced, get
medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give
anything by mouth because this material can enter the lungs and cause
severe lung damage. Get immediate medical attention.
(Continued on Page 3)
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Product: 203036 Preparation Date: 09/19/01 Page 3
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: -99 F LOWER EXPLOSIVE LIMIT: 1.0 %
UPPER EXPLOSIVE LIMIT: 9.5 %
AUTOIGNITION TEMPERATURE: ND
EXTINGUISHING MEDIA: DRY CHEMICAL FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 DEG. F. -
EXTREMELY FLAMMABLE LIQUID AND VAPOR! Water spray may be ineffective.
Closed containers may explode when exposed to extreme heat due to buildup
of steam. Closed containers may explode when exposed to extreme heat.
Vapors may form explosive mixtures with air. Vapors can travel to a source
of ignition and flash back. Keep containers tightly closed. Isolate from
heat, electrical equipment, sparks and open flame. Perforation of the
pressurized container may cause bursting of the can. Closed containers may
explode when exposed to extreme heat.
SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe
distance.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
+-------------------------------------------------------------------------+
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate the
area, remove all sources of ignition and ventilate well. Contain spilled
liquid with sand or earth. DO NOT use combustible materials such as
sawdust. Remove all sources of ignition, ventilate area and remove with
inert absorbent and non-sparking tools. Dispose of according to local,
state (provincial) and federal regulations. Do not incinerate closed
containers.
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| SECTION 7 - HANDLING AND STORAGE |
+-------------------------------------------------------------------------+
HANDLING: Wash thoroughly after handling. Wash hands before eating. Use
only in a well-ventilated area. Follow all MSDS/label precautions even
after container is emptied because it may retain product residues. Avoid
breathing vapor or mist.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical
equipment, sparks and open flame. Do not store above 120 degrees F. Store
large quantities in buildings designed and protected for storage of NFPA
Class I flammable liquids. Contents under pressure. Do not expose to heat
or store above 120 degrees F.
(Continued on Page 4)
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Product: 203036 Preparation Date: 09/19/01 Page 4
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
+-------------------------------------------------------------------------+
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation,
or other engineering controls to control airborne levels below recommended
exposure limits. Use explosion-proof ventilation equipment. Prevent
build-up of vapors by opening all doors and windows to achieve
cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying
respirator with an organic vapor cartridge or canister may be permissible
under certain circumstances where airborne concentrations are expected to
exceed exposure limits. Protection provided by air purifying respirators
is limited. Use a positive pressure air supplied respirator if there is
any potential for an uncontrolled release, exposure levels are not known,
or any other circumstances where air purifying respirators may not provide
adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and
absorption of this material through the skin. Nitrile or Neoprene gloves
may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of
liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial
hygienist for further information regarding personal protective equipment
and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating,
drinking or smoking.
+-------------------------------------------------------------------------+
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
+-------------------------------------------------------------------------+
BOILING RANGE : -34 - 383 F VAPOR DENSITY : Is heavier than air
ODOR : SOLVENT ODOR THRESHOLD : ND
APPEARANCE : LIQUID EVAPORATION RATE: Is faster than Ether
SOLUBILITY IN H2O : SOLUBLE
FREEZE POINT : ND SPECIFIC GRAVITY: 0.9611
VAPOR PRESSURE : ND pH @ 0.0 % : ND
PHYSICAL STATE : LIQUID VISCOSITY : ND
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
(See Section 16 for abbreviation legend)
+-------------------------------------------------------------------------+
| SECTION 10 - STABILITY AND REACTIVITY |
+-------------------------------------------------------------------------+
CONDITIONS TO AVOID: Avoid temperatures above 120 degrees F. Avoid all
possible sources of ignition.
(Continued on Page 5)
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Product: 203036 Preparation Date: 09/19/01 Page 5
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| SECTION 10 - STABILITY AND REACTIVITY |
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INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids
and strong alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: By open flame, carbon monoxide and
carbon dioxide. When heated to decomposition it emits acrid smoke and
irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
+-------------------------------------------------------------------------+
| SECTION 11 - TOXICOLOGICAL PROPERTIES |
+-------------------------------------------------------------------------+
COMPONENT TOXICOLOGICAL INFORMATION:
----------- CHEMICAL NAME ----------- ------ LD50 ------ ------ LC50 ------
LIQUIFIED PETROLEUM GAS N.E. N.E.
TOLUENE RAT 5000MG/KG MOUSE 5320PPM 8HR
ALIPHATIC PETROLEUM DISTILLATES No Information No Information
Hydrotreated Light Distillate No Information No Information
Calcium Carbonate (Limestone) No Information No Information
Stoddard Solvent 4900mg/kg(rat) N.E.
+-------------------------------------------------------------------------+
| SECTION 12 - ECOLOGICAL INFORMATION |
+-------------------------------------------------------------------------+
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
According to our raw material suppliers, all components are listed on the
TSCA inventory as required or meet the polymer exemption as defined in
Section 5.5.2 of the Toxic Substances Control Act.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
+-------------------------------------------------------------------------+
DISPOSAL METHOD: Dispose of material in accordance to local, state and
federal regulations and ordinances. Do not allow to enter storm drains or
sewer systems.
+-------------------------------------------------------------------------+
| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: AEROSOL
DOT TECHNICAL NAME:
DOT HAZARD CLASS: 2 HAZARD SUBCLASS: 1
(Continued on Page 6)
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Product: 203036 Preparation Date: 09/19/01 Page 6
+-------------------------------------------------------------------------+
| SECTION 14 - TRANSPORTATION INFORMATION |
+-------------------------------------------------------------------------+
DOT UN/NA NUMBER: UN1950 PACKING GROUP: RESP. GUIDE PAGE: 126
+-------------------------------------------------------------------------+
| SECTION 15 - REGULATORY INFORMATION |
+-------------------------------------------------------------------------+
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
CERCLA - SARA HAZARD CATEGORY:
This product has been reviewed according to the EPA 'Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % IS LESS THAN
TOLUENE 108-88-3 15.0 %
U.S. STATE REGULATIONS: AS FOLLOWS -
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
WATER DEIONIZED 7732-18-5
FLUORESCENT RESIN 39277-28-6
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
WATER DEIONIZED 7732-18-5
FLUORESCENT RESIN 39277-28-6
Barium Sulfate 7727-43-7
(Continued on Page 7)
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Product: 203036 Preparation Date: 09/19/01 Page 7
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| SECTION 15 - REGULATORY INFORMATION |
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CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer, birth defects or other
reproductive harm:
----------- CHEMICAL NAME ----------- CAS NUMBER
TOLUENE 108-88-3
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: A B5 D2A D2B
+-------------------------------------------------------------------------+
| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 2* FLAMMABILITY: 4 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 09/19/01
LEGEND: N.A. - Not Applicable, N.E. - Not Established,
N.D. - Not Determined
: No Information.
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The information contained on this MSDS has been checked and should be
accurate. However, it is the responsibility of the user to comply with all
Federal, State, and Local laws and regulations.
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